Please use this identifier to cite or link to this item: https://idr.l4.nitk.ac.in/jspui/handle/123456789/13433
Title: Thioacetamide as a releasing agent for the complexometric determination of thallium(iii) in its synthetic alloys and complexes
Authors: Karthikeyan, J.
Parameshwara, P.
Nityananda, Shetty, A.
Shetty, P.
Issue Date: 2007
Citation: Revue Roumaine de Chimie, 2007, Vol.52, 6, pp.611-615
Abstract: A simple and selective complexometric method for the determination of thallium is proposed, based on the masking ability of thioacetamide towards thallium(III). Thallium present in a given sample solution is first complexed with a known excess of EDTA and the surplus EDTA is titrated with standard zinc sulphate solution at pH 5-6 (hexamine buffer) using xylenol orange as the indicator. A 0.8% aqueous solution of thioacetamide is then added to displace EDTA from the TI(III)-EDTA complex. The released EDTA is titrated with standard zinc sulphate solution as before. Reproducible and accurate results are obtained for 0.018 - 0.371 mol L-1(3.79mg - 75.91mg) of Tl(III) with relative error less than 0.43% and coefficient of variation not more than 0.26%. The interference of various ions was studied and the method was used for the analysis of thallium in its synthetic alloy mixtures and also in complexes.
URI: http://idr.nitk.ac.in/jspui/handle/123456789/13433
Appears in Collections:1. Journal Articles

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